You have to keep in mind that the 48" OLED is not really a "drop it on the desk and use it" display for most people.
Most are going to find it uncomfortably large with poor ergonomics when you do that.
I would recommend that you at least buy a VESA arm or wall-mount it, to push the display back about a foot or so. Note that something hollow like an Ikea desk will not take the weight of a VESA arm.
Getting a keyboard tray/arm or a deeper desk to create mode distance may be beneficial, too.
I did both of these things back when I was using a 46" TV as a monitor.
David Zhang is a YouTuber that has used ultra-wide displays for years (including 32:9 models), and was sent a 48CX to review for his desk setup.
He has produced a few informative videos talking about its use at a desk:
So in terms of ease of setup, the G9 wins.
However, image quality is going to be no contest at all. The G9 is an edge-lit display with very few dimming zones. That cannot compared to an OLED.
Even G-Sync Ultimate monitors like the ASUS PG35VQ, which has hundreds of dimming zones, cannot compare to OLED when displaying darker scenes. They do look better in bright scenes, though.
There's also the issue of the G9 being a VA-type panel rather than IPS-type.
I think those are terrible due to the extremely limited viewing angle - which becomes more apparent on wider displays.
And that I don't think the 32:9 aspect ratio is a good choice for gaming.
In my experience, going to 21:9 is an improvement over 16:9 in practically every single way.
It is a drop-in replacement for a 16:9 monitor and expands the view horizontally to fill more of my vision.
The only real downside is that games are more demanding on your CPU from the wider view.
But 32:9 is wide enough that I have to sit further back from it than 16:9 or 21:9 for it to be comfortable, and that makes the image I'm seeing feel smaller.
I really feel that 32:9 is more of a productivity-focused change than a gaming one, as a replacement for a dual-monitor setup.
I'm waiting for that 43" LG that's coming personally. Not sure I would be happy with the pixel density on a monitor larger than that.
You may be waiting a while, since LG Electronics have not announced anything yet.
There has only been the announcement that LG Display plan on producing 43" OLED panels.
With the 48" OLED LGE announced a TV model at the same time that LGD started producing panels in that size - and it arrived late.
I really wish they would have announced a 5K ultra-wide panel for monitors, rather than a 43" 4K screen, though.